I have a couple of thoughts here:
1) It *might* just be related to electrical interference from things kicking on/off (you sometimes see dips when the heater kicks on), how close is the ORP probe line to anything which could cause line interference?
2) I don't think that the carbon would be affecting GFO directly, but perhaps as it removes organic matter from the water, it should be increasing the ORP by proxy as a result of a reduction organic matter which typically depresses ORP. However, that is the opposite of what your chart shows (ORP dips when reactors kick on).
3) I've gone round and round on this, because ORP is a ***** of a parameter, but I cant reason out why GFO would have a direct affect on ORP. It's not an open reaction of GFO & Tank water, as the Phosphate is binding to the Fe3+, which should keep the whole thing relatively neutral in terms of imbalanced charge. There are just a ton of parameters that affect ORP, and it's hard to suss out what is truly the causative agent here. You have to contend with variability in pH, dissolved oxygen, phosphate, flow rates in the reactor, etc.
By far the biggest modulator of ORP in reef tanks (assuming one is not running ozone) is going to be pH. Those pesky hydronium ions (i.e., an increase in H+ ions (H30+) or a reduction in pH) have a secondary oxidizing catalytic effect whereby other things are more effective oxidizers (increasing ORP).
You could test all these theories by taking one or both reactors offline for a day, but continuing to run the pump.